Fuel Cycle Chemistry

Actinide Chemistry

Since actinide chemistry is an important scientific field in numerous domains of nuclear energy, from fuel cycle to nuclear waste management, with the definition of deep site repository, the NSC workshop on Research and Development Needs for Actinide Chemistry will be held in autumn 2003 in Villeneuve-les-Avignon, Gard, France.


Speciation Technology

Speciation Techniques and Facilities for Radioactive Materials at Synchrotron Light Sources

The NSC workshop on this subject was held on 4-6 October 1998 in Grenoble, France, with approximately 100 participants from 13 countries. It was hosted by the European Synchrotron Radiation Facility (ESRF), and organised mainly by the Forschungszentrum Rossendorf, Germany. The European Commission, the CEA, France, and the U.S. DOE co-sponsored the meeting. The proceedings are currently being printed.

The 2nd Euroconference and NEA workshop on Speciation, Techniques, and Facilities for Radioactive Materials at Synchrotron Light Source was held at ESRF, Grenoble, on 12-13, September 2000.

Subsequent meetings were planned to be held every two years.

Evaluation of Speciation Technology

The NSC Workshop on Evaluation of Speciation Technologies was held at JAERI, Japan on 26-28 October 1999. The aim was to prepare a report on the advantages, disadvantages and limitations of various methods to study speciation of actinide and fission product elements in nuclear waste and nuclear reprocessing streams.Eleven invited papers and 27 posters were presented on recent progress and applications in each of the following five main topics:
  • Methods for Trace Concentration Speciation (<10-6M)
  • Methods for Macro Concentration Speciation(>10-6 M)
  • Methods for Empirical Formula and Molecular Structure Determination
  • Methods for Redox Speciation
  • Predictive Approach to Speciation
On the second and third days of the workshop, subgroups (according to the categories mentioned above) were set up to evaluate speciation technology. The aims of these subgroups were to examine speciation data that are needed, the advantages and limitations of the different methods that can be applied to obtain this data and suggestions for future R&D to improve existing methods or to develop new methods of speciation. The report, to be prepared through each subgroup discussion, would serve to guide researchers in choosing the most useful technique.

Pyrochemical Separations

A workshop on Pyrochemical Separations was held in Villeneuve-les-Avignon, France, on 14-15 March 2000. The workshop was co-organised by the European Commission and hosted by CEA-VALRHO. The topics included:
  • National and international R&D programs on pyrochemical separations,
  • Role and requirements of pyrochemical reprocessing in future fuel cycles
  • Recent progress in research activities:
    • Basic data (thermodynamics, reaction mechanisms, reaction kinetics, molecular modelling, etc.)
    • Results and experiences from process experiments
    • Process simulation and process design
  • Possible international collaboration. Recommendations for future NEA activities in the field will be proposed. The meeting was announced on the NEA Web page //www.oecd-nea.org/html/science/pyro.
The first meeting of the Pyrochemistry Working Group was held at OECD/NEA headquarters, Issy-les-Moulineaux, France, on 30-31 October 2000. This group is now one of the expert groups under Working Party on Scientific Issues in Partitioning and Transmutation (WPPT). Further information on this group can be found on the webpage //www.oecd-nea.org/html/science/wppt/working_area/cps (restricted access).

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