hexyl hexyl N,N-diethylcarbamoylmethylphosphinate

HHDECMP structure
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General infos Separation factors Distribution coefficients References
Abbreviation(s)

HHDECMP

Chemical group

carbamylalkylphosphonate

Formula

C18H38NO3P not CHON

Molecular mass

347.48 g/mol

Separation factors
Factor Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am(III)/Fe(III) 1.4 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 52 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 150 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 260 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 300 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 240 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 42 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 3.8 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [1]
Am/Fe 48 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Y 3.9 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Zr 19 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Mo 8.2 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Tc 1.9 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Ru 5.6 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Rh 480 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Pd 3.4 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/La 1.2 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Ce 1.1 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Pr 0.99 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Nd 1.1 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Sm 1.1 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Eu 1.2 0.35 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am/Fe 64 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Y 37 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Zr 1.8 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Mo 0.41 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Tc 16 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Ru 8.5 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Rh 640 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Pd 17 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/La 1.6 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Ce 1.3 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Pr 1.7 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Nd 1.5 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Sm 1.5 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Eu 1.3 0.35 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Fe 7.1 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/Y 2.3 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/Zr 0.04 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/Mo 1.2 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/Tc 74 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/Ru 9.6 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/Rh 530 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/Pd 59 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/La 1.5 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/Ce 1.2 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/Pr 0.96 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/Nd 1 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/Sm 0.99 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Am/Eu 1.1 0.35 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
Sc/La 3.7 0.33 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Distribution coefficients
Element Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am(III) 0.0479 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 1.32 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 2.7 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 4.71 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 7.35 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 10 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 11 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 9.6 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 0.0338 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 0.0252 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 0.0176 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 0.0178 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 0.0242 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 0.0424 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 0.26 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 2.55 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) ≈0.09 0.25 M   HNO3 0.25 M Tetrachloroethylene 25°C 1 min [2]
Am(III) ≈0.3 0.25 M   HNO3 0.5 M Tetrachloroethylene 25°C 1 min [2]
Am(III) ≈0.6 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am(III) ≈0.8 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am(III) ≈0.7 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
References

  1. doi:10.1080/01496398108057603

  2. doi:10.1080/07366298608917877