N,N'-dimethyl-N,N'-dioctylhexylethoxymalonamide

DMDOHEMA structure
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General infos Distribution coefficients Decontamination factors Tests Stability References
Abbreviation(s)

DMDOHEMA

Chemical group

malonamide

Formula

C29H58N2O3 CHON

Molecular mass

482.794 g/mol

Processes

Elements separated

An(III), Ln(III)

Country of origin

France

Country that has performed tests

France

Distribution coefficients
Element Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am241 2.1 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Y 0.32 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
La 1.69 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Ce(IV) 2.06 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Pr 2.04 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Nd 1.77 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Sm 0.36 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Eu 1.14 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Eu152 1.04 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Gd 1.32 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Zr 104 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Pd 3.69 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Ba <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Cd 0.19 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Mo 7.71 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Ni <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Sr <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Rb 0.09 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Ru 0.27 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Cr <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Cu <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Sb <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Sn <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Se <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Ce <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Cs <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Rh <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Te <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Al <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Na <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR [1]
Am241 2.65 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Y 0.4 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
La 2.13 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Ce(IV) 2.62 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Pr 2.52 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Nd 2.16 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Sm 1.67 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Eu 1.39 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Eu152 1.27 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Gd 1.84 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Zr 0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Pd 0.03 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Ba <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Cd 0.08 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Mo 2.07 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Ni <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Sr <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Rb 0.09 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Ru 0.28 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Cr <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Cu <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Sb <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Sn <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Se <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Ce <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Cs <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Rh <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Te <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Al <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Na <0.01 0.6 M   HNO3 3.1 M hydrogenated tetrapropene 22°C 15 min HAR; 0.05M CDTA [1]
Ln >100 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Zr >100 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Pd 4.2 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Mo 1.93 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Sr 1.43 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Se 0.77 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Fe 0.25 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Cd 0.25 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Ru 0.23 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Ba 0.13 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Cr ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Ni ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Rb ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Rn ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Sn ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Sb ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Te ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Cs ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Ln >100 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Zr ≤0.01 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Pd 0.07 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Mo 2.1 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Sr 2.25 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Se 0.74 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Fe 0.25 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Cd 0.17 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Ru 0.32 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Ba 0.2 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Cr ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Ni ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Rb ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Rn ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Sn ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Sb ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Te ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Cs ≤0.02 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Zr 30 0.5 M TODGA 0.2 M HNO3 1 M Exxsol-D80 22°C HAR [2]
Zr 86 0.5 M TODGA 0.2 M HNO3 2 M Exxsol-D80 22°C HAR [2]
Zr 142 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Zr 376 0.5 M TODGA 0.2 M HNO3 4 M Exxsol-D80 22°C HAR [2]
Zr ≤0.01 0.5 M TODGA 0.2 M HNO3 1 M Exxsol-D80 22°C HAR; 0.05M CDTA [2]
Zr ≤0.01 0.5 M TODGA 0.2 M HNO3 2 M Exxsol-D80 22°C HAR; 0.05M CDTA [2]
Zr ≤0.01 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR; 0.05M CDTA [2]
Zr 0.02 0.5 M TODGA 0.2 M HNO3 4 M Exxsol-D80 22°C HAR; 0.05M CDTA [2]
Mo 1.21 0.5 M TODGA 0.2 M HNO3 1 M Exxsol-D80 22°C HAR [2]
Mo 1.36 0.5 M TODGA 0.2 M HNO3 2 M Exxsol-D80 22°C HAR [2]
Mo 1.93 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR [2]
Mo 3.62 0.5 M TODGA 0.2 M HNO3 4 M Exxsol-D80 22°C HAR [2]
Mo 1.43 0.5 M TODGA 0.2 M HNO3 1 M Exxsol-D80 22°C HAR; 0.05M CDTA [2]
Mo 1.08 0.5 M TODGA 0.2 M HNO3 2 M Exxsol-D80 22°C HAR; 0.05M CDTA [2]
Mo 2.1 0.5 M TODGA 0.2 M HNO3 3 M Exxsol-D80 22°C HAR; 0.05M CDTA [2]
Mo 4.12 0.5 M TODGA 0.2 M HNO3 4 M Exxsol-D80 22°C HAR; 0.05M CDTA [2]
Rb 0.001 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Sr 0.012 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Y 1.74 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Zr 0.03 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Mo 0.26 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Ru 0.4 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Rh 0.014 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Pd 0.02 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Cd 0.013 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Te 0.001 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Cs 0.001 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Ba 0.028 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
La 5.8 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Ce 7.1 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Pr 7 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Nd 5.9 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Sm 4.7 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Eu 4 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Gd 3.6 1 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Rb 0.001 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Sr 0.006 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Y 0.9 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Zr 0.03 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Mo 0.22 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Ru 0.35 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Rh 0.01 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Pd 0.01 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Cd 0.008 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Te 0.001 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Cs 0.001 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Ba 0.024 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
La 2.8 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Ce 3.5 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Pr 3.4 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Nd 2.9 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Sm 2.4 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Eu 2 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Gd 1.9 0.65 M HEDTA 0.05 M HNO3 4.2 M hydrogenated tetrapropene   HAC; 0.2M C2H2O4 [3]
Am(III) ≈0.13 0.2 M   HNO3 3 M Dichloromethane 22°C 10 min [4]
Am(III) ≈0.27 0.2 M   HNO3 4 M Dichloromethane 22°C 10 min [4]
Am(III) ≈0.35 0.2 M   HNO3 5 M Dichloromethane 22°C 10 min [4]
Am(III) 0.056 0.2 M   HNO3 3 M Tetrachloroethane 22°C 10 min [4]
Am(III) ≈0.15 0.2 M   HNO3 4 M Tetrachloroethane 22°C 10 min [4]
Am(III) ≈0.26 0.2 M   HNO3 5 M Tetrachloroethane 22°C 10 min [4]
Eu(III) 0.024 0.2 M   HNO3 3 M Tetrachloroethane 22°C 10 min [4]
Am(III) 0.049 0.2 M   HNO3 3 M 1-Octanol 22°C 10 min [4]
Eu(III) 0.033 0.2 M   HNO3 3 M 1-Octanol 22°C 10 min [4]
Am(III) 0.052 0.2 M   HNO3 3 M hydrogenated tetrapropene/1-Octanol, 1:1 22°C 10 min [4]
Eu(III) 0.035 0.2 M   HNO3 3 M hydrogenated tetrapropene/1-Octanol, 1:1 22°C 10 min [4]
Am(III) 0.078 0.2 M   HNO3 3 M hydrogenated tetrapropene/1-Octanol, 10% 22°C 10 min [4]
Eu(III) 0.045 0.2 M   HNO3 3 M hydrogenated tetrapropene/1-Octanol, 10% 22°C 10 min [4]
Decontamination factors
Element Value Conc. Add. ligand Aq. acid Organic diluent Temp. Additional Stages Ref.
Rb 1 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Y 1.2 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Y 325 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Sr 1 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Mo 1 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Zr 1 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Tc 4 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Tc 5 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Ru 1.04 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Ru 3 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Rh 1 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Pd 1 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Ag 1 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Cd 1 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Sn 1 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Sb 1 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Te 1 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Cs 1 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
La 525 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Ce 800 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Pr 1150 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Nd 650 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Sm 230 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Eu >60 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Gd >30 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Tb >70 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Dy >130 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Np 3 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Am 2250 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
Cm >320 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   extraction; 0.1M oxalic acid; org/aq=1 12 [5]
La 12000 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Ce 5000 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Pr 30000 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Nd 40000 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Sm 25000 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Eu 3400 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Gd 7500 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Tb 2200 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Dy 5000 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Np 60 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Am 200000 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Cm 20000 0.65 M HEDTA 0.01 M HNO3 3.9 M hydrogenated tetrapropene   back-extraction; 0.1M oxalic acid; org/aq=1 16 [5]
Am243 4800 0.65 M HEDTA 0.01 M HNO3 3.7 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Cm244 300 0.65 M HEDTA 0.01 M HNO3 3.7 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Am243 >100000 0.65 M HEDTA 0.01 M HNO3 3.7 M hydrogenated tetrapropene   0.1M C2H2O4 16 [6]
Cm244 >36000 0.65 M HEDTA 0.01 M HNO3 3.7 M hydrogenated tetrapropene   0.1M C2H2O4 16 [6]
Rb 0.95 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Sr 0.84 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Y 150 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Zr 1 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Mo 1.08 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Ru 1.27 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Rh 0.97 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Pd 0.98 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Cd 0.97 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Te 0.99 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Cs 0.91 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Ba 0.96 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
La 1109 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Ce 1513 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Pr 1972 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Nd 4146 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Sm 4389 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Eu 1624 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Gd 1732 1 M HEDTA 0.05 M HNO3 4.1 M hydrogenated tetrapropene   0.1M C2H2O4 12 [6]
Tests
Test carried out Test type Conditions Ref.
Tests on surrogate, spiked, or genuine PUREX Raffinates [7]
Extraction ALONE TPH  
Stability
Type of study Conditions Ref.
Hydrolysis 2 months, 0.01M CyMe4BTBP + 0.25M DMDOHEMA in n-octanol [8]
Hydrolysis 25°C, 60°C; 4months [9]
Radiolysis Gamma Radiolysis, 0.75MGy [9]
References

  1. 10.1080/07366299.2012.700591

  2. 10.1016/j.proche.2012.10.061

  3. 10.1080/01496390601120763

  4. doi:10.1524/ract.2008.1485

  5. doi:10.1524/ract.93.6.351.65642

  6. 10.1524/ract.92.8.475.39283

  7. doi:10.1080/18811248.2007.9711302 https://doi.org/10.1016/S1631-0705(02)01370-1

  8. doi:10.1080/07366290600761936

  9. doi:10.1081/SS-100103616