dihexyl N,N-diethylcarbamoylmethylphosphine oxide

DHDECMPO structure
PNG ChemDraw
General infos Separation factors Distribution coefficients References
Abbreviation(s)

DHDECMPO

Chemical group

carbamylalkylphosphine oxide

Formula

C18H38NO2P not CHON

Molecular mass

331.481 g/mol

Separation factors
Factor Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am(III)/Fe(III) 0.19 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 5 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 5.8 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 6.1 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 5.2 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 1.8 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 0.1 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 0.0099 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Eu(III) 1.06 0.5 M   HNO3 0.10 M xylene 25°C 1 min [2]
Am(III)/Eu(III) 1.02 0.5 M   HNO3 0.25 M xylene 25°C 1 min [2]
Am(III)/Eu(III) 1.01 0.5 M   HNO3 0.50 M xylene 25°C 1 min [2]
Am(III)/Eu(III) 1.12 0.5 M   HNO3 1.0 M xylene 25°C 1 min [2]
Am(III)/Eu(III) 1.25 0.5 M   HNO3 2.0 M xylene 25°C 1 min [2]
Am(III)/Eu(III) 1.32 0.5 M   HNO3 3.0 M xylene 25°C 1 min [2]
Am(III)/Eu(III) 1.28 0.5 M   HNO3 4.0 M xylene 25°C 1 min [2]
Am(III)/Eu(III) 1.05 0.5 M   HNO3 6.0 M xylene 25°C 1 min [2]
Am/Fe 12 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Y 2.9 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Zr 2.2 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Mo 0.59 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Tc 4.7 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Ru 18 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Rh 750 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Pd 4 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/La 2.5 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Ce 1.5 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Pr 1 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Nd 1.2 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Sm 1.1 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Eu 0.95 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Fe 0.49 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Y 1.8 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Zr 0.02 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Mo 0.08 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Tc 6.4 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Ru 69 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Rh 130 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Pd 4.6 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/La 3 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Ce 1.6 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Pr 1.3 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Nd 1.2 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Sm 1 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Eu 1.1 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Fe 0.05 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Y 0.98 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Zr 0.25 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Mo 0.3 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Tc 15 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Ru 5.3 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Rh 110 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Pd 9.7 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/La 2.8 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Ce 1.4 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Pr 1.1 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Nd 1.1 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Sm 0.84 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Eu 0.85 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Sc/La 128 0.24 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Distribution coefficients
Element Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am(III) 0.419 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 27.7 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 80.7 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 105 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 76.4 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 33.2 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 17.5 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 15.5 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 2.16 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 5.54 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 13.9 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 17.3 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 14.7 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 18 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 175 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 1570 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) ≈25 0.25 M   HNO3 0.25 M Tetrachloroethylene 25°C 1 min [3]
Am(III) ≈30 0.25 M   HNO3 0.5 M Tetrachloroethylene 25°C 1 min [3]
Am(III) ≈18 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am(III) ≈2.2 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am(III) ≈1.5 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Fe 4.5 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Y 1.2 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Zr 110 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Mo 28 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Tc 0.34 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Ru 0.32 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Rh 0.02 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Pd 0.48 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
La 0.73 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Ce 1.4 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Pr 1.7 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Nd 1.8 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Sm 2.2 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Eu 2 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am 2.2 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
References

  1. doi:10.1080/01496398108057603

  2. doi:10.1080/01496398208060649

  3. doi:10.1080/07366298608917877