dihexyl N,N-diethylcarbamoylmethylphosphonate

DHDECMP structure
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General infos Separation factors Distribution coefficients References
Abbreviation(s)

DHDECMP

Chemical group

carbamylalkylphosphonate

Formula

C18H38NO4P not CHON

Molecular mass

363.479 g/mol

Separation factors
Factor Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am/Eu 1.66 0.817 M   HNO3 1 M diisopropylbenzene 25°C [1]
Am/Gd 2.48 0.817 M   HNO3 1 M diisopropylbenzene 25°C [1]
Am/Tb 2.85 0.817 M   HNO3 1 M diisopropylbenzene 25°C [1]
Am/Dy 3.76 0.817 M   HNO3 1 M diisopropylbenzene 25°C [1]
Am/Ho 5.37 0.817 M   HNO3 1 M diisopropylbenzene 25°C [1]
Am/Er 7.5 0.817 M   HNO3 1 M diisopropylbenzene 25°C [1]
Am/Tm 11.1 0.817 M   HNO3 1 M diisopropylbenzene 25°C [1]
Am/Yb 14.9 0.817 M   HNO3 1 M diisopropylbenzene 25°C [1]
Am/Lu 21 0.817 M   HNO3 1 M diisopropylbenzene 25°C [1]
Am/Y 9.67 0.817 M   HNO3 1 M diisopropylbenzene 25°C [1]
Am/Cm 1.58 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Bk 1.28 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Cf 1.39 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Es 1.77 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Fm 2.1 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Ce 0.906 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Pm 1.1 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Sm 1.2 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Eu 1.41 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Gd 1.92 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Tb 3.17 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Tm 8.21 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Yb 9.68 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Y 5.06 0.817 M   HNO3 5 M diisopropylbenzene 25°C [1]
Am/Cm 1.8 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Bk 1.38 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Cf 1.28 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Es 1.5 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Fm 1.5 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/La 0.648 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Ce 0.694 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Pr 0.836 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Nd 0.986 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Pm 1.22 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Sm 1.35 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Eu 1.68 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Gd 2.32 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Tb 2.82 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Dy 3.13 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Ho 4.15 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Er 5.38 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Tm 8.41 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Yb 9.58 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Lu 15.3 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am/Y 7.63 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [1]
Am(III)/Fe(III) 1600 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [2]
Am(III)/Fe(III) 5100 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [2]
Am(III)/Fe(III) 4900 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III)/Fe(III) 4100 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III)/Fe(III) 3000 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III)/Fe(III) 580 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [2]
Am/Y 6.6 0.7 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Zr 36 0.7 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Mo 18 0.7 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Tc 0.44 0.7 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Ru 5.6 0.7 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/La 0.87 0.7 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Ce 0.91 0.7 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Pr 0.95 0.7 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Nd 1.2 0.7 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Sm 1.5 0.7 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Eu 1.6 0.7 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [3]
Am/Fe 70 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Y 6.1 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Zr 28 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Mo 47 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Tc 10 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Ru 10 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Rh 700 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Pd 14 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/La 0.88 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Ce 0.91 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Pr 1 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Nd 1.1 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Sm 1.4 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Eu 1.5 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Fe 62 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Y 3 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Zr 0.62 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Mo 33 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Tc 58 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Ru 9.5 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Rh 620 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Pd 69 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/La 0.95 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Ce 0.9 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Pr 0.84 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Nd 0.98 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Sm 1 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Am/Eu 1.1 0.5 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [3]
Sc/La 0.35 0.49 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am/Eu 1.71 0.817 M   HNO3 0.5 M diisopropylbenzene 25°C [3]
Am/Eu 1.66 0.817 M   HNO3 1 M diisopropylbenzene 25°C [3]
Am/Eu 1.62 0.817 M   HNO3 2 M diisopropylbenzene 25°C [3]
Am/Eu 1.57 0.817 M   HNO3 3 M diisopropylbenzene 25°C [3]
Am/Eu 1.5 0.817 M   HNO3 4 M diisopropylbenzene 25°C [3]
Am/Eu 1.41 0.817 M   HNO3 5 M diisopropylbenzene 25°C [3]
Am/Eu 1.66 0.817 M   diisopropylbenzene 25°C 0.5M LiNO3 [3]
Am/Eu 1.68 0.817 M   diisopropylbenzene 25°C 1M LiNO3 [3]
Am/Eu 1.57 0.817 M   diisopropylbenzene 25°C 2M LiNO3 [3]
Am/Eu 1.41 0.817 M   diisopropylbenzene 25°C 3M LiNO3 [3]
Am/Eu 1.24 0.817 M   diisopropylbenzene 25°C 4M LiNO3 [3]
Am/Eu 1.26 0.817 M   diisopropylbenzene 25°C 5M LiNO3 [3]
Am/Cm 1.54 0.817 M   HNO3 1 M diisopropylbenzene 25°C [3]
Am/Bk 1.39 0.817 M   HNO3 1 M diisopropylbenzene 25°C [3]
Am/Cf 1.46 0.817 M   HNO3 1 M diisopropylbenzene 25°C [3]
Am/Es 1.68 0.817 M   HNO3 1 M diisopropylbenzene 25°C [3]
Am/Fm 1.74 0.817 M   HNO3 1 M diisopropylbenzene 25°C [3]
Am/La 0.708 0.817 M   HNO3 1 M diisopropylbenzene 25°C [3]
Am/Ce 0.738 0.817 M   HNO3 1 M diisopropylbenzene 25°C [3]
Am/Pr 0.828 0.817 M   HNO3 1 M diisopropylbenzene 25°C [3]
Am/Nd 1.04 0.817 M   HNO3 1 M diisopropylbenzene 25°C [3]
Am/Pm 1.17 0.817 M   HNO3 1 M diisopropylbenzene 25°C [3]
Am/Sm 1.36 0.817 M   HNO3 1 M diisopropylbenzene 25°C [3]
Distribution coefficients
Element Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Mo 0.03 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Tc 0.14 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Ru 0.14 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Rh 0.002 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Pd 0.1 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
La 1.6 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Ce 1.5 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Pr 1.4 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Nd 1.3 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Sm 1 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Eu 0.93 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am 1.4 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [3]
Am(III) 0.00339 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 0.0077 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 0.0343 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 0.121 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 0.4 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 1.11 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 2.41 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 2.51 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 0.0000215 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 0.0000237 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 0.0000811 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 0.000274 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 0.000799 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [3]
Fe(III) 0.00432 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [3]
Am(III) 1.3 0.5 M   Tetrachloroethylene 25°C 1 min 8.0M LiCl [4]
Am(III) 2.2 0.5 M   Tetrachloroethylene 25°C 1 min 3.0M LiNO3 [4]
Am 2.75 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Cm 1.53 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Bk 1.99 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Cf 2.15 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Es 1.83 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Fm 1.83 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
La 4.24 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Ce 3.96 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Pr 3.29 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Nd 2.79 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Pm 2.25 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Sm 2.04 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Eu 1.64 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Gd 1.19 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Tb 0.976 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Dy 0.878 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Ho 0.663 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Er 0.511 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Tm 0.327 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Yb 0.287 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Lu 0.18 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Y 0.36 0.817 M   diisopropylbenzene 25°C 1 min 1M LiNO3 [4]
Am 1.17 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Cm 0.76 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Bk 0.841 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Cf 0.801 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Es 0.696 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Fm 0.672 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
La 1.65 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Ce 1.59 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Pr 1.41 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Nd 1.12 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Pm 1 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Sm 0.86 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Eu 0.705 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Gd 0.472 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Tb 0.41 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Dy 0.311 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Ho 0.218 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Er 0.156 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Tm 0.105 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Yb 0.0786 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Lu 0.0558 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Y 0.121 0.817 M   HNO3 1 M diisopropylbenzene 25°C 1 min [4]
Am 8.18 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Cm 5.18 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Bk 6.42 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Cf 5.88 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Es 4.62 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Fm 3.9 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Ce 9.03 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Pm 7.44 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Sm 6.82 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Eu 5.8 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Gd 4.26 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Tb 2.58 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Tm 1.3 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Yb 1.02 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Y 1.62 0.817 M   HNO3 5 M diisopropylbenzene 25°C 1 min [4]
Am(III) ≈0.002 0.25 M   HNO3 0.25 M Tetrachloroethylene 25°C 1 min [4]
Am(III) ≈0.006 0.25 M   HNO3 0.5 M Tetrachloroethylene 25°C 1 min [4]
Am(III) ≈0.025 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [4]
Am(III) ≈0.18 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [4]
Am(III) ≈0.28 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [4]
Fe 0.02 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [4]
Y 0.23 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [4]
Zr 0.05 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [4]
References

  1. doi:10.1080/01496398108068530

  2. doi:10.1080/01496398108057603

  3. doi:10.1080/07366298608917877

  4. doi:10.1080/07366298708918575