dihexyl N,N-dibutylcarbamoylmethylphosphine oxide

DHDBCMPO structure
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General infos Separation factors Distribution coefficients References
Abbreviation(s)

DHDBCMPO

Chemical group

carbamylalkylphosphine oxide

Formula

C22H46NO2P not CHON

Molecular mass

387.589 g/mol

Separation factors
Factor Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am(III)/Fe(III) 0.58 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 2 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 4.9 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 1.3 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 1.8 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 0.61 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 0.095 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 0.011 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [1]
Am/Fe 6.3 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Y 1.7 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Zr 0.02 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Mo 0.12 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Tc 4.6 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Ru 40 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Rh 100 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Pd 1.9 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/La 3.8 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Ce 1.7 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Pr 1.4 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Nd 1.2 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Sm 0.92 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Eu 0.92 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Distribution coefficients
Element Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am(III) 3.41 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 38.4 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 152 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 104 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 88.4 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 25.3 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 10.2 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 6.67 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 5.9 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 19.1 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 31.3 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 80.4 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 49.4 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 41.8 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 107 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 611 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe 0.19 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Y 0.71 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Zr 60 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Mo 10 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Tc 0.26 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Ru 0.03 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Rh 0.012 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Pd 6.3 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
La 0.32 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Ce 0.71 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Pr 0.86 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Nd 1 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Sm 1.3 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Eu 1.3 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am 1.2 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
References

  1. doi:10.1080/01496398108057603

  2. doi:10.1080/07366298608917877