dihexyl N,N-diisobutylcarbamoylmethylphosphine oxide

DHD(IB)CMPO structure
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General infos Separation factors Distribution coefficients References
Abbreviation(s)

DHD(IB)CMPO

Chemical group

carbamylalkylphosphine oxide

Formula

C22H46NO2P not CHON

Molecular mass

387.589 g/mol

Separation factors
Factor Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am(III)/Fe(III) 0.45 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 23 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 24 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 23 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 14 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 3.8 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 0.41 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 0.046 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [1]
Am/Fe 6.1 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Y 1.4 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Zr 0.02 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Mo 0.12 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Tc 3.9 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Ru 69 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Rh 92 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Pd 2.4 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/La 3.8 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Ce 1.6 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Pr 1.2 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Nd 1.1 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Sm 0.79 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Eu 0.79 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Distribution coefficients
Element Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am(III) 3.65 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 144 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 210 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 172 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 71.4 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 19.7 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 6.05 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 4.34 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 8.05 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 6.36 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 8.72 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 7.44 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 5.21 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 5.25 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 14.7 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 93.4 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe 0.18 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Y 0.79 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Zr 55 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Mo 9.2 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Tc 0.28 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Ru 0.016 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Rh 0.012 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Pd 0.46 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
La 0.29 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Ce 0.69 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Pr 0.92 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Nd 1 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Sm 1.4 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Eu 1.4 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am 1.1 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am ≈50 0.25 M   HNO3 0.25 M Tetrachloroethylene 25°C 1 min [2]
Am ≈48 0.25 M   HNO3 0.5 M Tetrachloroethylene 25°C 1 min [2]
Am ≈23 0.25 M   HNO3 1 M Tetrachloroethylene 25°C 1 min [2]
Am ≈1.2 0.25 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am ≈0.3 0.25 M   HNO3 6 M Tetrachloroethylene 25°C 1 min [2]
References

  1. doi:10.1080/01496398108057603

  2. doi:10.1080/07366298608917877