di(2-ethylbutyl) N,N-diethylcarbamoylmethylphosphine oxide

D(EB)DECMPO structure
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General infos Separation factors Distribution coefficients References
Abbreviation(s)

D(EB)DECMPO

Chemical group

carbamylalkylphosphine oxide

Formula

C18H38NO2P not CHON

Molecular mass

331.481 g/mol

Separation factors
Factor Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am(III)/Fe(III) 0.06 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 0.53 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 2 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 2.3 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 2.8 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 1.3 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 0.2 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [1]
Am(III)/Fe(III) 0.024 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [1]
Am/Fe 2.9 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Y 3.3 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Zr 0.02 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Mo 0.17 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Ru 35 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Rh 230 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Pd 1.5 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/La 2.8 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Ce 1.6 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Pr 1.2 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Nd 1.3 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Sm 1.3 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am/Eu 1.4 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Distribution coefficients
Element Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am(III) 0.0521 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 0.598 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 1.91 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 2.63 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 2.2 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 1.24 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 0.92 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [2]
Am(III) 1.25 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 0.865 0.5 M   HNO3 0.01 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 1.18 0.5 M   HNO3 0.10 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 0.979 0.5 M   HNO3 0.25 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 1.12 0.5 M   HNO3 0.50 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 0.78 0.5 M   HNO3 1.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 0.952 0.5 M   HNO3 2.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 4.57 0.5 M   HNO3 4.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe(III) 51.8 0.5 M   HNO3 6.00 M p-diisopropylbenzene 25°C 1 min [2]
Fe 0.24 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Y 0.21 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Zr 40 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Mo 4.2 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Ru 0.02 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Rh 0.003 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Pd 0.46 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
La 0.25 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Ce 0.43 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Pr 0.57 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Nd 0.53 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Sm 0.54 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Eu 0.49 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
Am 0.7 0.5 M   HNO3 3 M Tetrachloroethylene 25°C 1 min [2]
References

  1. doi:10.1080/01496398108057603

  2. doi:10.1080/07366298608917877