6,6'-bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-benzo[1,2,4]triazin-3-yl)-[2,2'] bipyridine

CyMe4BTBP structure
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General infos Separation factors Distribution coefficients Decontamination factors Stability Solubility References
Abbreviation(s)

CyMe4BTBP

Chemical group

bis-triazinyl-bipyridine

Formula

C32H38N8 CHON

Molecular mass

534.712 g/mol

Processes

Elements separated

An(III)

Country of origin

Germany, UK, France, Sweden

Country that has performed tests

Germany, UK, France, Sweden, Czech Republic, Italy, Poland

Separation factors
Factor Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am(III)/Eu(III) ≈44.08 0.01 M DMDOHEMA 0.75 M HNO3 1 M n-octanol 25°C 5 min [1]
Am(III)/Eu(III) ≈47.11 0.01 M DMDOHEMA 0.75 M HNO3 1 M n-octanol 25°C 15 min [1]
Am(III)/Eu(III) ≈44.57 0.01 M DMDOHEMA 0.75 M HNO3 1 M n-octanol 25°C 60 min [1]
Am(III)/Eu(III) ≈30.93 0.01 M DMDOHEMA 1 M HNO3 1 M n-octanol 25°C 5 min [1]
Am(III)/Eu(III) ≈40.79 0.01 M DMDOHEMA 1 M HNO3 1 M n-octanol 25°C 15 min [1]
Am(III)/Eu(III) ≈26.78 0.01 M DMDOHEMA 1 M HNO3 1 M n-octanol 25°C 60 min [1]
Am(III)/Eu(III) ≈67.00 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 1 min [1]
Am(III)/Eu(III) ≈95.65 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 2 min [1]
Am/Eu >100     [2]
Am(III)/Eu(III) ≈46.59 0.02 M   HNO3 0.5 M n-octanol 25°C 5 min [2]
Am(III)/Eu(III) ≈124.78 0.02 M   HNO3 0.5 M n-octanol 25°C 30 min [2]
Am(III)/Eu(III) ≈139.39 0.02 M   HNO3 0.5 M n-octanol 25°C 60 min [2]
Am(III)/Eu(III) ≈144.10 0.02 M   HNO3 0.5 M n-octanol 25°C 120 min [2]
Am(III)/Eu(III) ≈131.88 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 5 min [2]
Am(III)/Eu(III) ≈120.71 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 15 min [2]
Am(III)/Eu(III) ≈108.06 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 60 min [2]
Am(III)/Eu(III) ≈80.14 0.01 M DMDOHEMA 0.5 M HNO3 1 M n-octanol 25°C 5 min [2]
Am(III)/Eu(III) ≈77.52 0.01 M DMDOHEMA 0.5 M HNO3 1 M n-octanol 25°C 15 min [2]
Am(III)/Eu(III) ≈72.54 0.01 M DMDOHEMA 0.5 M HNO3 1 M n-octanol 25°C 60 min [2]
Distribution coefficients
Element Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Th232 0.2772407996741774 0.0005 M   HNO3 1 M cyclohexanone   5 min [3]
Th232 0.27271830293654736 0.001 M   HNO3 1 M cyclohexanone   5 min [3]
Th232 0.2682695795279726 0.005 M   HNO3 1 M cyclohexanone   5 min [3]
Th232 0.239095514427051 0.01 M   HNO3 1 M cyclohexanone   5 min [3]
U235 0.9210553176894817 0.0005 M   HNO3 1 M cyclohexanone   5 min [3]
U235 0.9597162693679221 0.001 M   HNO3 1 M cyclohexanone   5 min [3]
U235 1 0.005 M   HNO3 1 M cyclohexanone   5 min [3]
U235 0.9210553176894817 0.01 M   HNO3 1 M cyclohexanone   5 min [3]
U238 0.8767123872968682 0.0005 M   HNO3 1 M cyclohexanone   5 min [3]
U238 0.9060305822453377 0.001 M   HNO3 1 M cyclohexanone   5 min [3]
U238 0.9597162693679221 0.005 M   HNO3 1 M cyclohexanone   5 min [3]
U238 0.8986103751927311 0.01 M   HNO3 1 M cyclohexanone   5 min [3]
Np237 0.43222938178368175 0.0005 M   HNO3 1 M cyclohexanone   5 min [3]
Np237 0.5956621435290105 0.001 M   HNO3 1 M cyclohexanone   5 min [3]
Np237 1.8682223847710375 0.005 M   HNO3 1 M cyclohexanone   5 min [3]
Np237 3.2147178163573797 0.01 M   HNO3 1 M cyclohexanone   5 min [3]
Am(III) ≈1.25 0.02 M   HNO3 0.5 M n-octanol 25°C 5 min [3]
Am(III) ≈3.72 0.02 M   HNO3 0.5 M n-octanol 25°C 30 min [3]
Am(III) ≈4.52 0.02 M   HNO3 0.5 M n-octanol 25°C 60 min [3]
Am(III) ≈4.52 0.02 M   HNO3 0.5 M n-octanol 25°C 120 min [3]
Eu(III) ≈0.03 0.02 M   HNO3 0.5 M n-octanol 25°C 5 min [3]
Eu(III) ≈0.03 0.02 M   HNO3 0.5 M n-octanol 25°C 30 min [3]
Eu(III) ≈0.03 0.02 M   HNO3 0.5 M n-octanol 25°C 60 min [3]
Eu(III) ≈0.03 0.02 M   HNO3 0.5 M n-octanol 25°C 120 min [3]
Am(III) ≈3.32 0.01 M DMDOHEMA 1 M HNO3 1 M n-octanol 25°C 5 min non-equilibrated organic phase [3]
Am(III) ≈3.83 0.01 M DMDOHEMA 1 M HNO3 1 M n-octanol 25°C 15 min non-equilibrated organic phase [3]
Am(III) ≈3.04 0.01 M DMDOHEMA 1 M HNO3 1 M n-octanol 25°C 60 min non-equilibrated organic phase [3]
Am(III) ≈4.52 0.01 M DMDOHEMA 0.75 M HNO3 1 M n-octanol 25°C 5 min non-equilibrated organic phase [3]
Am(III) ≈4.28 0.01 M DMDOHEMA 0.75 M HNO3 1 M n-octanol 25°C 15 min non-equilibrated organic phase [3]
Am(III) ≈3.79 0.01 M DMDOHEMA 0.75 M HNO3 1 M n-octanol 25°C 60 min non-equilibrated organic phase [3]
Am(III) ≈4.62 0.01 M DMDOHEMA 0.5 M HNO3 1 M n-octanol 25°C 5 min non-equilibrated organic phase [3]
Am(III) ≈5.11 0.01 M DMDOHEMA 0.5 M HNO3 1 M n-octanol 25°C 15 min non-equilibrated organic phase [3]
Am(III) ≈5.58 0.01 M DMDOHEMA 0.5 M HNO3 1 M n-octanol 25°C 60 min non-equilibrated organic phase [3]
Am(III) ≈4.83 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 5 min non-equilibrated organic phase [3]
Am(III) ≈5.46 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 15 min non-equilibrated organic phase [3]
Am(III) ≈4.94 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 60 min non-equilibrated organic phase [3]
Am(III) ≈2.59 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 1 min pre-equilibrated organic phase with nitric acid prior to extraction, and equilibrium nitric acid concentration in the aqueous phase was 0.96 M [3]
Am(III) ≈5.38 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 2 min pre-equilibrated organic phase with nitric acid prior to extraction, and equilibrium nitric acid concentration in the aqueous phase was 0.96 M [3]
Am(III) ≈9.36 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 5 min pre-equilibrated organic phase with nitric acid prior to extraction, and equilibrium nitric acid concentration in the aqueous phase was 0.96 M [3]
Am(III) ≈9.78 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 15 min pre-equilibrated organic phase with nitric acid prior to extraction, and equilibrium nitric acid concentration in the aqueous phase was 0.96 M [3]
Am(III) ≈9.36 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 60 min pre-equilibrated organic phase with nitric acid prior to extraction, and equilibrium nitric acid concentration in the aqueous phase was 0.96 M [3]
Eu(III) ≈0.04 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 1 min pre-equilibrated organic phase with nitric acid prior to extraction, and equilibrium nitric acid concentration in the aqueous phase was 0.96 M [3]
Eu(III) ≈0.06 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 2 min pre-equilibrated organic phase with nitric acid prior to extraction, and equilibrium nitric acid concentration in the aqueous phase was 0.96 M [3]
Eu(III) ≈0.07 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 5 min pre-equilibrated organic phase with nitric acid prior to extraction, and equilibrium nitric acid concentration in the aqueous phase was 0.96 M [3]
Eu(III) ≈0.08 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 15 min pre-equilibrated organic phase with nitric acid prior to extraction, and equilibrium nitric acid concentration in the aqueous phase was 0.96 M [3]
Eu(III) ≈0.08 0.01 M DMDOHEMA 0.25 M HNO3 1 M n-octanol 25°C 60 min pre-equilibrated organic phase with nitric acid prior to extraction, and equilibrium nitric acid concentration in the aqueous phase was 0.96 M [3]
Eu(III)γ ≈0.00 0.005 M DMDOHEMA 0.25 M HNO3 0.116 M n-octanol 20°C 5 min [3]
Eu(III)γ ≈0.00 0.005 M DMDOHEMA 0.25 M HNO3 0.218 M n-octanol 20°C 5 min [3]
Eu(III)γ ≈0.01 0.005 M DMDOHEMA 0.25 M HNO3 0.536 M n-octanol 20°C 5 min [3]
Eu(III)γ ≈0.02 0.005 M DMDOHEMA 0.25 M HNO3 0.969 M n-octanol 20°C 5 min [3]
Eu(III)γ ≈0.06 0.005 M DMDOHEMA 0.25 M HNO3 1.88 M n-octanol 20°C 5 min [3]
Cm(III)α ≈0.02 0.005 M DMDOHEMA 0.25 M HNO3 0.116 M n-octanol 20°C 5 min [3]
Cm(III)α ≈0.08 0.005 M DMDOHEMA 0.25 M HNO3 0.218 M n-octanol 20°C 5 min [3]
Cm(III)α ≈0.43 0.005 M DMDOHEMA 0.25 M HNO3 0.536 M n-octanol 20°C 5 min [3]
Cm(III)α ≈1.40 0.005 M DMDOHEMA 0.25 M HNO3 0.969 M n-octanol 20°C 5 min [3]
Cm(III)α ≈3.07 0.005 M DMDOHEMA 0.25 M HNO3 1.88 M n-octanol 20°C 5 min [3]
Am(III)γ ≈0.04 0.005 M DMDOHEMA 0.25 M HNO3 0.116 M n-octanol 20°C 5 min [3]
Am(III)γ ≈0.12 0.005 M DMDOHEMA 0.25 M HNO3 0.218 M n-octanol 20°C 5 min [3]
Am(III)γ ≈0.65 0.005 M DMDOHEMA 0.25 M HNO3 0.536 M n-octanol 20°C 5 min [3]
Am(III)γ ≈2.20 0.005 M DMDOHEMA 0.25 M HNO3 0.969 M n-octanol 20°C 5 min [3]
Am(III)γ ≈4.55 0.005 M DMDOHEMA 0.25 M HNO3 1.88 M n-octanol 20°C 5 min [3]
Am(III)α ≈0.04 0.005 M DMDOHEMA 0.25 M HNO3 0.116 M n-octanol 20°C 5 min [3]
Am(III)α ≈0.12 0.005 M DMDOHEMA 0.25 M HNO3 0.218 M n-octanol 20°C 5 min [3]
Am(III)α ≈0.62 0.005 M DMDOHEMA 0.25 M HNO3 0.536 M n-octanol 20°C 5 min [3]
Am(III)α ≈2.20 0.005 M DMDOHEMA 0.25 M HNO3 0.969 M n-octanol 20°C 5 min [3]
Am(III)α ≈4.41 0.005 M DMDOHEMA 0.25 M HNO3 1.88 M n-octanol 20°C 5 min [3]
Eu(III)γ ≈0.00 0.01 M DMDOHEMA 0.25 M HNO3 0.116 M n-octanol 20°C 5 min [3]
Eu(III)γ ≈0.00 0.01 M DMDOHEMA 0.25 M HNO3 0.218 M n-octanol 20°C 5 min [3]
Eu(III)γ ≈0.02 0.01 M DMDOHEMA 0.25 M HNO3 0.536 M n-octanol 20°C 5 min [3]
Eu(III)γ ≈0.07 0.01 M DMDOHEMA 0.25 M HNO3 0.969 M n-octanol 20°C 5 min [3]
Eu(III)γ ≈0.14 0.01 M DMDOHEMA 0.25 M HNO3 1.88 M n-octanol 20°C 5 min [3]
Cm(III)α ≈0.10 0.01 M DMDOHEMA 0.25 M HNO3 0.116 M n-octanol 20°C 5 min [3]
Cm(III)α ≈0.26 0.01 M DMDOHEMA 0.25 M HNO3 0.218 M n-octanol 20°C 5 min [3]
Cm(III)α ≈1.40 0.01 M DMDOHEMA 0.25 M HNO3 0.536 M n-octanol 20°C 5 min [3]
Cm(III)α ≈4.83 0.01 M DMDOHEMA 0.25 M HNO3 0.969 M n-octanol 20°C 5 min [3]
Cm(III)α ≈7.17 0.01 M DMDOHEMA 0.25 M HNO3 1.88 M n-octanol 20°C 5 min [3]
Am(III)γ ≈0.15 0.01 M DMDOHEMA 0.25 M HNO3 0.116 M n-octanol 20°C 5 min [3]
Am(III)γ ≈0.45 0.01 M DMDOHEMA 0.25 M HNO3 0.218 M n-octanol 20°C 5 min [3]
Am(III)γ ≈2.34 0.01 M DMDOHEMA 0.25 M HNO3 0.536 M n-octanol 20°C 5 min [3]
Am(III)γ ≈7.85 0.01 M DMDOHEMA 0.25 M HNO3 0.969 M n-octanol 20°C 5 min [3]
Am(III)γ ≈14.38 0.01 M DMDOHEMA 0.25 M HNO3 1.88 M n-octanol 20°C 5 min [3]
Am(III)α ≈0.15 0.01 M DMDOHEMA 0.25 M HNO3 0.116 M n-octanol 20°C 5 min [3]
Am(III)α ≈0.40 0.01 M DMDOHEMA 0.25 M HNO3 0.218 M n-octanol 20°C 5 min [3]
Am(III)α ≈2.20 0.01 M DMDOHEMA 0.25 M HNO3 0.536 M n-octanol 20°C 5 min [3]
Am(III)α ≈6.95 0.01 M DMDOHEMA 0.25 M HNO3 0.969 M n-octanol 20°C 5 min [3]
Am(III)α ≈9.41 0.01 M DMDOHEMA 0.25 M HNO3 1.88 M n-octanol 20°C 5 min [3]
Am(III) ≈0.13 0.002 M DMDOHEMA 0.25 M HNO3 0.02 M n-octanol 20°C 5 min 0.5M NH4NO3 [3]
Am(III) ≈0.26 0.003 M DMDOHEMA 0.25 M HNO3 0.02 M n-octanol 20°C 5 min 0.5M NH4NO3 [3]
Am(III) ≈0.74 0.005 M DMDOHEMA 0.25 M HNO3 0.02 M n-octanol 20°C 5 min 0.5M NH4NO3 [3]
Am(III) ≈1.35 0.007 M DMDOHEMA 0.25 M HNO3 0.02 M n-octanol 20°C 5 min 0.5M NH4NO3 [3]
Am(III) ≈2.40 0.01 M DMDOHEMA 0.25 M HNO3 0.02 M n-octanol 20°C 5 min 0.5M NH4NO3 [3]
Eu(III) ≈0.01 0.002 M DMDOHEMA 0.25 M HNO3 0.02 M n-octanol 20°C 5 min 0.5M NH4NO3 [3]
Eu(III) ≈0.01 0.003 M DMDOHEMA 0.25 M HNO3 0.02 M n-octanol 20°C 5 min 0.5M NH4NO3 [3]
Eu(III) ≈0.01 0.005 M DMDOHEMA 0.25 M HNO3 0.02 M n-octanol 20°C 5 min 0.5M NH4NO3 [3]
Eu(III) ≈0.02 0.007 M DMDOHEMA 0.25 M HNO3 0.02 M n-octanol 20°C 5 min 0.5M NH4NO3 [3]
Eu(III) ≈0.03 0.01 M DMDOHEMA 0.25 M HNO3 0.02 M n-octanol 20°C 5 min 0.5M NH4NO3 [3]
Am(III) ≈0.17 0.002 M   HNO3 0.02 M n-octanol 20°C 5 min 1M NH4NO3 [3]
Am(III) ≈0.34 0.003 M   HNO3 0.02 M n-octanol 20°C 5 min 1M NH4NO3 [3]
Am(III) ≈1.18 0.005 M   HNO3 0.02 M n-octanol 20°C 5 min 1M NH4NO3 [3]
Am(III) ≈3.32 0.008 M   HNO3 0.02 M n-octanol 20°C 5 min 1M NH4NO3 [3]
Am(III) ≈5.67 0.01 M   HNO3 0.02 M n-octanol 20°C 5 min 1M NH4NO3 [3]
Am(III) ≈11.82 0.015 M   HNO3 0.02 M n-octanol 20°C 5 min 1M NH4NO3 [3]
Eu(III) ≈0.00 0.002 M   HNO3 0.02 M n-octanol 20°C 5 min 1M NH4NO3 [3]
Eu(III) ≈0.00 0.003 M   HNO3 0.02 M n-octanol 20°C 5 min 1M NH4NO3 [3]
Eu(III) ≈0.01 0.005 M   HNO3 0.02 M n-octanol 20°C 5 min 1M NH4NO3 [3]
Eu(III) ≈0.02 0.008 M   HNO3 0.02 M n-octanol 20°C 5 min 1M NH4NO3 [3]
Eu(III) ≈0.03 0.01 M   HNO3 0.02 M n-octanol 20°C 5 min 1M NH4NO3 [3]
Eu(III) ≈0.06 0.015 M   HNO3 0.02 M n-octanol 20°C 5 min 1M NH4NO3 [3]
Y 0.04 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
La <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Ce <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Pr 0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Nd 0.02 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Sm 0.07 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Eu 0.16 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Gd 0.08 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Ni 30 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Cu 4.88 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Zr 0.5 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Mo 2.57 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Pd 6.19 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Ag 0.88 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Cd 12.3 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Cr 0.02 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Sn 0.12 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Sb 0.12 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Rb 0.08 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Ru 0.09 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Rh <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Te 0.03 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Sr <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Ba <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Cs <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR [4]
Y 0.85 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
La 0.02 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Ce 0.03 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Pr 0.04 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Nd 0.06 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Sm 0.14 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Eu 0.24 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Gd 0.17 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Ni 18.4 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Cu 15.7 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Zr 0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Mo 0.21 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Pd 8.81 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Ag 2.48 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Cd 6.92 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Cr 0.03 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Sn 0.31 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Sb 0.07 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Rb 0.1 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Ru 0.07 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Rh <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Te <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Sr <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Ba <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Cs <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 [4]
Y 0.15 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
La 0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Ce 0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Pr 0.02 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Nd 0.04 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Sm 0.1 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Eu 0.14 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Gd 0.08 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Ni 32.1 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Cu 19.1 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Zr 0.23 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Mo 3.76 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Pd 6.63 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Ag 3.59 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Cd 14.2 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Cr 0.03 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Sn 0.46 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Sb 0.09 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Rb 0.11 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Ru 0.1 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Rh <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Te 0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Sr 0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Ba <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Cs <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.05M HEDTA [4]
Y 0.73 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
La 0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Ce 0.02 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Pr 0.03 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Nd 0.05 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Sm 0.13 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Eu 0.25 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Gd 0.15 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Ni 37.3 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Cu 5.6 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Zr 0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Mo 0.18 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Pd 4.69 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Ag 0.51 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Cd 4.03 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Cr 0.04 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Sn 0.05 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Sb 0.08 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Rb 0.09 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Ru 0.05 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Rh <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Te <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Sr <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Ba <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Cs <0.01 0.015 M TODGA 0.005 M HNO3 3.2 M hydrogenated tetrapropene/1-Octanol, 4:6 22°C 15 min HAR; 0.3M C2H2O4 + 0.05M HEDTA [4]
Decontamination factors
Element Value Conc. Add. ligand Aq. acid Organic diluent Temp. Additional Stages Ref.
Y 1 0.015 M DMDOHEMA 0.25 M HNO3 2 M n-Octanol   TODGA Process Product 12 [5]
La 1 0.015 M DMDOHEMA 0.25 M HNO3 2 M n-Octanol   TODGA Process Product 12 [5]
Ce 1 0.015 M DMDOHEMA 0.25 M HNO3 2 M n-Octanol   TODGA Process Product 12 [5]
Pr 1 0.015 M DMDOHEMA 0.25 M HNO3 2 M n-Octanol   TODGA Process Product 12 [5]
Nd 1 0.015 M DMDOHEMA 0.25 M HNO3 2 M n-Octanol   TODGA Process Product 12 [5]
Sm 1 0.015 M DMDOHEMA 0.25 M HNO3 2 M n-Octanol   TODGA Process Product 12 [5]
Eu 1 0.015 M DMDOHEMA 0.25 M HNO3 2 M n-Octanol   TODGA Process Product 12 [5]
Gd 1 0.015 M DMDOHEMA 0.25 M HNO3 2 M n-Octanol   TODGA Process Product 12 [5]
Am >7000 0.015 M DMDOHEMA 0.25 M HNO3 2 M n-Octanol   TODGA Process Product 12 [5]
Cm >1000 0.015 M DMDOHEMA 0.25 M HNO3 2 M n-Octanol   TODGA Process Product 12 [5]
Stability
Type of study Conditions Ref.
Hydrolysis 2 months, 0.01M CyMe4BTBP + 0.25M DMDOHEMA in n-octanol [5]
Radiolysis 200 kGy; impact on separation process [6]
Radiolysis 100, 500, 1075 kGy [7]
Hydrolysis 11-67days, 8-55days [7]
Radiolysis [8]
Radiolysis Gamma Radiolysis, 0.3MGy [9]
Solubility
Solvent Solubility Temperature Ref.
hydrogenated tetrapropylene/n-octanol 0.01 M   [9]
n-octanol 0.02 M   [9]
References

  1. doi:10.1080/07366290600761936

  2. https://www.oecd-nea.org/science/pubs/2018/7267-soar.pdf

  3. doi:10.1080/07366290701416000

  4. 10.1080/07366299.2011.539122

  5. doi:10.1080/07366290802672204

  6. 10.1016/j.proche.2016.10.025

  7. CEA

  8. doi:10.1007/s10967-014-3021-5

  9. doi:10.1016/j.proche.2016.10.005