2,6-bis[5-(2,2-dimethyl-propyl)-1H-pyrazol-3-yl]-pyridine

C5-BPP structure

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General infos Separation factors Distribution coefficients Decontamination factors References

Abbreviation(s)

C5-BPP

Chemical group

pyridine

Formula

C₂₁H₂₉N₅ CHON

Molecular mass

351.498 g/mol

Separation factors

Factor	Value	Conc.	Add. ligand	Aq. acid	Organic diluent	Temp.	Contact time	Additional	Ref.
Amγ/Cmγ	4.3	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8		30 min	single centrifugal contactor test; calc SF = 4.8	[1]
Amγ/Euγ	460	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8		30 min	single centrifugal contactor test;	[1]
Am(III)/Eu(III)	≈70.45	0.01 M		HNO₃ 0.2 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Am(III)/Eu(III)	≈96.34	0.01 M		HNO₃ 0.3 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Am(III)/Eu(III)	≈97.79	0.01 M		HNO₃ 0.5 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Am(III)/Eu(III)	≈113.51	0.01 M		HNO₃ 0.7 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Am(III)/Eu(III)	≈124.12	0.01 M		HNO₃ 1.2 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]

Distribution coefficients

Element	Value	Conc.	Add. ligand	Aq. acid	Organic diluent	Temp.	Contact time	Additional	Ref.
Amγ	3.44	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8		30 min	single centrifugal contactor test; calc DC = 3.48	[2]
Euγ	0.007	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8		30 min	single centrifugal contactor test;	[2]
Amα	3.73	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8		30 min	single centrifugal contactor test; calc DC = 3.48	[2]
Cmα	0.86	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8		30 min	single centrifugal contactor test; calc DC = 0.72	[2]
Cfα	0.57	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8		30 min	single centrifugal contactor test;	[2]
Am(III)	≈262	0.01 M		HNO₃ 0.2 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Am(III)	≈71.5	0.01 M		HNO₃ 0.3 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Am(III)	≈12.5	0.01 M		HNO₃ 0.5 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Am(III)	≈3.58	0.01 M		HNO₃ 0.7 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Am(III)	≈1.22	0.01 M		HNO₃ 1 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Am(III)	≈0.894	0.01 M		HNO₃ 1.1 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Am(III)	≈0.625	0.01 M		HNO₃ 1.2 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Eu(III)	≈3.74	0.01 M		HNO₃ 0.2 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Eu(III)	≈0.748	0.01 M		HNO₃ 0.3 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Eu(III)	≈0.125	0.01 M		HNO₃ 0.5 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Eu(III)	≈0.0313	0.01 M		HNO₃ 0.7 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Eu(III)	≈0.00978	0.01 M		HNO₃ 1 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Eu(III)	≈0.00748	0.01 M		HNO₃ 1.1 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]
Eu(III)	≈0.00523	0.01 M		HNO₃ 1.2 M	kerosene	20°C	45 min	0.5M 2-bromohexanoic acid	[2]

Decontamination factors

Element	Value	Conc.	Add. ligand	Aq. acid	Organic diluent	Temp.	Additional	Stages	Ref.
Eu152γ	0.9	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8			16	[2]
Am241γ	1306	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8		calc DF = 573	16	[2]
Am241α	>1000	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8		calc DF = 573	16	[2]
Cm244α	0.92	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8			16	[2]
Cf252α	0.89	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8			16	[2]
Eu152γ	7693	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8			24	[2]
Cm244α	214	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8		calc DF = 77	24	[2]
Cf252α	1744	0.4 M	TEHP 0.15 M	HNO₃ 0.13 M	isooctane/tert-butyl benzene, 2:8			24	[2]

References

doi:10.1524/ract.2010.1708
doi:10.1021/ic3000526