bis(chlorophenyl)dithiophosphinic acid

(ClPh)2PSSH structure
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General infos Separation factors Distribution coefficients Stability References
Abbreviation(s)

(ClPh)2PSSH

Chemical group

Formula

C12H9Cl2PS2 not CHON

Molecular mass

319.198 g/mol

Processes

Separation factors
Factor Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am/Eu 31.2 0.5 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [1]
Am/Eu 28.1 0.5 M TBP 0.25 M HNO3 0.4 M toluene 21°C 10 min [1]
Am/Eu 27.9 0.5 M TOPO 0.25 M HNO3 0.2 M toluene 21°C 10 min [1]
Am/Eu 25.1 0.5 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [1]
Am/Eu 182 0.5 M   HNO3 0.4 M toluene 21°C 10 min [1]
Am/Eu 6 0.25 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [1]
Am/Eu 27 0.5 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [1]
Am/Eu 53 0.75 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [1]
Am/Eu 88 1 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [1]
Am(III)/Cm(III) ≈13.33 0.4 M TEHP 0.15 M HNO3 0.053 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III)/Cm(III) ≈10.78 0.4 M TEHP 0.15 M HNO3 0.078 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III)/Cm(III) ≈8.94 0.4 M TEHP 0.15 M HNO3 0.152 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III)/Cm(III) ≈9.32 0.4 M TEHP 0.15 M HNO3 0.196 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III)/Cm(III) ≈0.96 0.4 M TEHP 0.15 M HNO3 0.298 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III)/Cm(III) ≈6.34 0.4 M TEHP 0.15 M HNO3 0.5 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III)/Cm(III) ≈11.05 0.4 M TEHP 0.15 M HNO3 0.053 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III)/Cm(III) ≈9.76 0.4 M TEHP 0.15 M HNO3 0.078 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III)/Cm(III) ≈9.35 0.4 M TEHP 0.15 M HNO3 0.103 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III)/Cm(III) ≈9.15 0.4 M TEHP 0.15 M HNO3 0.154 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III)/Cm(III) ≈6.96 0.4 M TEHP 0.15 M HNO3 0.2 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III)/Cm(III) ≈7.25 0.4 M TEHP 0.15 M HNO3 0.3 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III)/Cm(III) ≈5.47 0.4 M TEHP 0.15 M HNO3 0.498 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III)/Cm(III) ≈10.00 0.4 M TEHP 0.15 M HNO3 0.053 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III)/Cm(III) ≈9.21 0.4 M TEHP 0.15 M HNO3 0.079 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III)/Cm(III) ≈9.18 0.4 M TEHP 0.15 M HNO3 0.1 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III)/Cm(III) ≈10.23 0.4 M TEHP 0.15 M HNO3 0.154 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III)/Cm(III) ≈7.39 0.4 M TEHP 0.15 M HNO3 0.2 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III)/Cm(III) ≈5.29 0.4 M TEHP 0.15 M HNO3 0.312 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III)/Cm(III) ≈4.30 0.4 M TEHP 0.15 M HNO3 0.49 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III)γ/Eu(III)γ 637 0.4 M TEHP 0.15 M HNO3 0.13 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III)α/Cm(III)α 7.3 0.4 M TEHP 0.15 M HNO3 0.13 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Distribution coefficients
Element Value Conc. Add. ligand Aq. acid Organic diluent Temp. Contact time Additional Ref.
Am(III) ≈2 0.5 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Am(III) ≈5.01 0.5 M TBP 0.5 M HNO3 0.2 M toluene 21°C 10 min [2]
Am(III) ≈8.91 0.5 M TBP 0.8 M HNO3 0.2 M toluene 21°C 10 min [2]
Am(III) ≈10 0.5 M TBP 1 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) ≈0.006 0.5 M TBP 0.1 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) ≈0.06 0.5 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) ≈0.56 0.5 M TBP 0.5 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) ≈2.24 0.5 M TBP 0.8 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) ≈4 0.5 M TBP 1 M HNO3 0.2 M toluene 21°C 10 min [2]
Ce(III) ≈30 0.5 M TBP 0.25 M HNO3 0.01 M toluene 21°C 10 min [2]
Nd(III) ≈10 0.5 M TBP 0.25 M HNO3 0.01 M toluene 21°C 10 min [2]
Pr(III) ≈20 0.5 M TBP 0.25 M HNO3 0.01 M toluene 21°C 10 min [2]
Ce(III) ≈4 0.5 M TBP 0.25 M HNO3 0.05 M toluene 21°C 10 min [2]
Nd(III) ≈1 0.5 M TBP 0.25 M HNO3 0.05 M toluene 21°C 10 min [2]
Pr(III) ≈2 0.5 M TBP 0.25 M HNO3 0.05 M toluene 21°C 10 min [2]
Ce(III) ≈0.8 0.5 M TBP 0.25 M HNO3 0.1 M toluene 21°C 10 min [2]
Nd(III) ≈0.4 0.5 M TBP 0.25 M HNO3 0.1 M toluene 21°C 10 min [2]
Pr(III) ≈0.5 0.5 M TBP 0.25 M HNO3 0.1 M toluene 21°C 10 min [2]
Ce(III) ≈0.1 0.5 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Nd(III) ≈0.04 0.5 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Pr(III) ≈0.04 0.5 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Ce(III) ≈0.01 0.5 M TBP 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Nd(III) ≈0.006 0.5 M TBP 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Pr(III) ≈0.006 0.5 M TBP 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Am(III) 2.13 0.5 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) 0.068 0.5 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Am(III) 0.19 0.5 M TBP 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Eu(III) 0.0068 0.5 M TBP 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Am(III) 152.25 0.5 M TOPO 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) 5.46 0.5 M TOPO 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Am(III) 15.85 0.5 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Eu(III) 0.632 0.5 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Am(III) ≈200 0.5 M TOPO 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Am(III) ≈15 0.5 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Am(III) ≈4 0.5 M TOPO 0.25 M HNO3 0.6 M toluene 21°C 10 min [2]
Am(III) ≈0.8 0.5 M TOPO 0.25 M HNO3 1 M toluene 21°C 10 min [2]
Eu(III) ≈5 0.5 M TOPO 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) ≈0.6 0.5 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Eu(III) ≈0.2 0.5 M TOPO 0.25 M HNO3 0.6 M toluene 21°C 10 min [2]
Eu(III) ≈0.08 0.5 M TOPO 0.25 M HNO3 1 M toluene 21°C 10 min [2]
Am(III) ≈4.5 0.25 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Am(III) ≈13 0.5 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Am(III) ≈24 0.75 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Am(III) ≈40 1 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Eu(III) ≈0.7 0.25 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Eu(III) ≈0.5 0.5 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Eu(III) ≈0.4 0.75 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Eu(III) ≈0.4 1 M TOPO 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Am(III) ≈0.4 0.5 M   HNO3 0.4 M toluene 21°C 10 min [2]
Eu(III) ≈0.002 0.5 M   HNO3 0.4 M toluene 21°C 10 min [2]
Am(III) ≈143 0.4 M TEHP 0.15 M HNO3 0.053 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III) ≈47.5 0.4 M TEHP 0.15 M HNO3 0.08 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III) ≈22.1 0.4 M TEHP 0.15 M HNO3 0.1 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III) ≈6.65 0.4 M TEHP 0.15 M HNO3 0.15 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III) ≈2.21 0.4 M TEHP 0.15 M HNO3 0.196 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III) ≈0.511 0.4 M TEHP 0.15 M HNO3 0.3 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III) ≈0.0931 0.4 M TEHP 0.15 M HNO3 0.5 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Am(III) ≈84.5 0.4 M TEHP 0.15 M HNO3 0.053 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III) ≈30.9 0.4 M TEHP 0.15 M HNO3 0.078 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III) ≈14.7 0.4 M TEHP 0.15 M HNO3 0.1 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III) ≈4.32 0.4 M TEHP 0.15 M HNO3 0.154 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III) ≈1.43 0.4 M TEHP 0.15 M HNO3 0.2 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III) ≈0.383 0.4 M TEHP 0.15 M HNO3 0.3 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III) ≈0.0715 0.4 M TEHP 0.15 M HNO3 0.498 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III) ≈54.9 0.4 M TEHP 0.15 M HNO3 0.053 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III) ≈17.8 0.4 M TEHP 0.15 M HNO3 0.079 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III) ≈9.53 0.4 M TEHP 0.15 M HNO3 0.1 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III) ≈2.87 0.4 M TEHP 0.15 M HNO3 0.154 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III) ≈0.976 0.4 M TEHP 0.15 M HNO3 0.2 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III) ≈0.187 0.4 M TEHP 0.15 M HNO3 0.312 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III) ≈0.0453 0.4 M TEHP 0.15 M HNO3 0.49 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Cm(III) ≈11.0 0.4 M TEHP 0.15 M HNO3 0.053 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Cm(III) ≈4.42 0.4 M TEHP 0.15 M HNO3 0.078 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Cm(III) ≈2.15 0.4 M TEHP 0.15 M HNO3 0.104 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Cm(III) ≈0.750 0.4 M TEHP 0.15 M HNO3 0.152 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Cm(III) ≈0.237 0.4 M TEHP 0.15 M HNO3 0.196 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Cm(III) ≈0.0649 0.4 M TEHP 0.15 M HNO3 0.298 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Cm(III) ≈0.0147 0.4 M TEHP 0.15 M HNO3 0.5 M tert-butyl benzene/iso-octane, 20%   15 min 0.25M NaNO3 [2]
Cm(III) ≈7.87 0.4 M TEHP 0.15 M HNO3 0.053 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Cm(III) ≈3.16 0.4 M TEHP 0.15 M HNO3 0.078 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Cm(III) ≈1.58 0.4 M TEHP 0.15 M HNO3 0.103 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Cm(III) ≈0.499 0.4 M TEHP 0.15 M HNO3 0.154 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Cm(III) ≈0.210 0.4 M TEHP 0.15 M HNO3 0.2 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Cm(III) ≈0.0576 0.4 M TEHP 0.15 M HNO3 0.3 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Cm(III) ≈0.0130 0.4 M TEHP 0.15 M HNO3 0.498 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am ≈4000 0.5 M TBP 0.25 M HNO3 0.01 M toluene 21°C 10 min [2]
Am ≈200 0.5 M TBP 0.25 M HNO3 0.05 M toluene 21°C 10 min [2]
Am ≈30 0.5 M TBP 0.25 M HNO3 0.1 M toluene 21°C 10 min [2]
Am ≈2 0.5 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Am ≈0.2 0.5 M TBP 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Eu ≈200 0.5 M TBP 0.25 M HNO3 0.01 M toluene 21°C 10 min [2]
Eu ≈9 0.5 M TBP 0.25 M HNO3 0.05 M toluene 21°C 10 min [2]
Eu ≈0.8 0.5 M TBP 0.25 M HNO3 0.1 M toluene 21°C 10 min [2]
Eu ≈0.06 0.5 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu ≈0.006 0.5 M TBP 0.25 M HNO3 0.4 M toluene 21°C 10 min [2]
Am(III) ≈0.04 0.1 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Am(III) ≈0.5 0.25 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Am(III) ≈2 0.5 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Am(III) ≈5.01 0.8 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Am(III) ≈7.08 1 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) ≈0.003 0.1 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) ≈0.02 0.25 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) ≈0.03 0.5 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) ≈0.13 0.8 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Eu(III) ≈0.2 1 M TBP 0.25 M HNO3 0.2 M toluene 21°C 10 min [2]
Am(III) ≈0.5 0.5 M TBP 0.1 M HNO3 0.2 M toluene 21°C 10 min [2]
Cm(III) ≈15.4 0.4 M TEHP 0.15 M HNO3 0.053 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Cm(III) ≈2.00 0.4 M TEHP 0.15 M HNO3 0.079 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Cm(III) ≈1.02 0.4 M TEHP 0.15 M HNO3 0.1 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Cm(III) ≈0.280 0.4 M TEHP 0.15 M HNO3 0.154 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Cm(III) ≈0.133 0.4 M TEHP 0.15 M HNO3 0.2 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Cm(III) ≈0.0365 0.4 M TEHP 0.15 M HNO3 0.312 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Cm(III) ≈0.0107 0.4 M TEHP 0.15 M HNO3 0.49 M tert-butyl benzene/iso-octane, 20%   15 min 1M NaNO3 [2]
Am(III)γ 4.64 0.4 M TEHP 0.15 M HNO3 0.13 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Eu(III)γ 0.007 0.4 M TEHP 0.15 M HNO3 0.13 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Am(III)α 4.6 0.4 M TEHP 0.15 M HNO3 0.13 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Cm(III)α 0.63 0.4 M TEHP 0.15 M HNO3 0.13 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Cf(III)α 0.52 0.4 M TEHP 0.15 M HNO3 0.13 M tert-butyl benzene/iso-octane, 20%   15 min 0.5M NaNO3 [2]
Stability
Type of study Conditions Ref.
Hydrolysis room temperature, 175 days [3]
Radiolysis gamma-spectrum, 0.8 MeV in average, 20 kGy/h [3]
Radiolysis gamma-spectrum, 4 kGy/h, distribution coefficients [3]
References

  1. doi:10.1080/07360299908934599

  2. doi:10.1524/ract.2010.1708

  3. doi:10.1081/SEI-120003021